catena-Poly[[bis(acetato-κ2O,O′)cobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl-κ2N3:N3′]
نویسندگان
چکیده
منابع مشابه
catena-Poly[[trimethyltin(IV)]-μ-cyclohex-3-ene-1-carboxylato]
The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H⋯O...
متن کاملcatena-Poly[cadmium-μ-[1,3-bis(imidazol-1-yl)propane]-di-μ-chlorido]
The title complex, [CdCl(2)(C(9)H(12)N(4))](n), is characterized by the formation of a zigzag chain structure parallel to [001]. In the chain, the Cd(2+) cation is coordinated by four bridging Cl(-) ligands in equatorial positions and two N atoms from symmetry-related and likewise bridging 1,3-bis-(imidazol-1-yl)propane ligands in axial positions, forming a distorted CdCl(4)N(2) octa-hedron.
متن کاملcatena-Poly[[tetra-μ-formato-κ8 O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ2 N 1:N 5]
In the title polymeric compound, [Cu2(HCO2)4(C6H12N4)] n , the Cu(II) atom is five-coordinated in a square-pyramidal geometry that is defined by four O atoms from four formate ligands and one N atom from a hexa-methyl-ene-tetra-mine ligand. The two Cu(II) atoms are separated by 2.6850 (7) Å, and together with the four formate ligands they form a paddle-wheel unit. The hexa-mine ligand uses only...
متن کاملcatena-Poly[trimethylphenylammonium [[bromidocadmate(II)]-μ-bromido-μ-chlorido]]
In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.
متن کاملcatena-Poly[heptylenediammonium [[tetrachloridobismuthate(III)]-μ-chlorido]]
The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]} n , consists of distorted corner-joined [BiCl6] octa-hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl-enedi-ammonium cations. The asymmetric unit contains two crystallographically independent bis-muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s160053681004715x